superheavy elements

hermanntrude

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Jun 23, 2006
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This is a topic i've always been interested in, but also always a littl ignorant of it, but the time seems to be right for us to watch this space.

The heaviest elements found in nature are uranium, neptunium and plutonium. But these aren't the heaviest elements found.

What defines an element is it's proton number; literally the number of protons in their nucleii. The simplest element is hydrogen which has a single proton, and, uniquely, no neutrons. After hydrogen we have helium which usually has 2 protons and 2 neutrons, although sometimes a helium atom exists with only one neutron. This is an example of an isotope, which is an atom with the same amount of protons and a different amount of neutrons. Some elements have more than one stable isotope. For instance bromine has two: bromine-81 and bromine-79. the numbers relate to the mass of the isotopes, which is the sum of protons and neutrons, so bromine 81 has 35 protons and 46 neutrons.

The reason that nucleii hold together is that there is a force between particles, known as the strong nuclear force, which can overcome the repulsion between the positively charged protons. that's why you need a few neutrons as well as protons to hold everything together. Neutrons add to the strong nuclear force but don't add to the repulsive forces between the protons.

So when you get to elements as large as, for instance, seaborgium (element 106, which, when i first studied chemistry, was known only as unnilhexium), you need a lot of neutrons. seaborgium has 106 protons and 165 neutrons, in its most stable isotope.

Now when I say stable, i mean more stable than the other isotopes. Seaborgium-271 has a half-life of 1.9 minutes, which means if i have a gram of seaborgium, 1.9 minutes later i'll only have 0.5 grams left, because it will have decayed, probably into rutherfordium, element 104. As we head further up the periodic table, the elements generally (but not always) get less stable.

the interesting thing about superheavy elements is that some of the heaviest elements are more stable than you might imagine. Roentgenium, element 111, has a half-life of 3.6 seconds. Now that's fairly short, but some scientists would have predicted it didn't exist for more than a femtosecond.

discoveries such as these made nuclear physicists invent a new kind of physics which helped explain these obsevations, and predict new elements. Seaborg, a scientist who discovered more elements than any other, predicted a "map" of stability. Basically it's a graph of the number of protons, versus the number of neutrons in each element. Each square on this map represents a possible isotope, and is shown as a bar, representing the length of the half life of the isotope, or as a blank, representing an isotope which is unstable.



The interesting thing about this map is that it shows us that there may be some so-far undiscovered isotopes which are surprisingly stable. One such isotope is the fabled 114th element, which is said to be particularly stable. Particularly, the isotope 298-UUq might be stable enough for people to actually see and hold in their hand.

Element 114 has already been isolated, but not the isotope the scientists are hoping for. the most stable isotope yet found is 289-UUq, which has a half-life of 2.6 seconds. It is thought that 298-UUq might have a half-life measurable in years.

Even more interesting is that there are more than one of these "maps" based on slightly different science. And some of these maps predict that element 122 might be particularly stable. recently, a group from a middle-eastern university claim that they discovered element 122 in a sample of thorium (LINK). If their claim is held to be true (the paper is not yet peer-reviewed), then it might prove that there are more elements to be found in the far reaches of the map.

So if element 122 does exist... where does it belong on the periodic table? examine the periodic table below and think on the question for a while:



If you count up the proton numbers, you'll see that the row is finished at 118. So perhaps 122 goes on the row beneath? Well yes, but there's more to it than that. In fact, element 122 would be the first ever discovered "g-block" element. If the claim holds true, the entire periodic table will have to be re-organized to show it in its correct position. Wikipedia contains a proposed new periodic table (LINK).

Someone recently asked me what was the point of this stuff... in his words "how many mouths will it feed?". I thought about it for a while and then remembered what Faraday said when he was asked what use his electricity might have:

"what use is a newborn baby?"
 

darkbeaver

the universe is electric
Jan 26, 2006
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Hermanntrude, we all understand the potential of the newborn baby. Could you expand a bit about what you see as the potential of the new element, just for those of us who may not have the same powers of vision as you.
 

hermanntrude

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Jun 23, 2006
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Hermanntrude, we all understand the potential of the newborn baby. Could you expand a bit about what you see as the potential of the new element, just for those of us who may not have the same powers of vision as you.

that's exactly my point. I can't tell you what good Amelia (my baby) will do for the world, but i'm sure she has potential. The same applies to unbibium (element 122). IF, it is stable, it surely has uses. it might even turn out to be a cure for cancer, or it might be useful for fuel cells or for something totally un-thought-of.

The above examples are only suggestions, and are probably wrong. however, some people thought that fire was stupid and dangerous, i expect, and some people believed the computer was pointless.
 

Tonington

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Oct 27, 2006
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That's interesting, thanks for the great post Hermann. G-block orbitals, that's pretty neat. Must be fun for the chemists to ponder and speculate. :D
 

karrie

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Jan 6, 2007
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lol... it's so tempting to call you all geeks right now... but I think spending all my time here makes me one too, so I'll abstain. ;-)
 

hermanntrude

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Jun 23, 2006
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That's interesting, thanks for the great post Hermann. G-block orbitals, that's pretty neat. Must be fun for the chemists to ponder and speculate. :D

yeah it's really neat. The existance of g-orbitals has long been predicted, so it would be interesting to see them in action.

and new stable elements, and even a possible totally complete periodic table (it's predicted to be complete at 138 elements, since any larger than that would require electrons to move at the speed of light)... it's all so exciting.

And yes i'm a geek, who cares?
 

Tonington

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Oct 27, 2006
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Have you seen the pre-print for the unbibium paper Hermann, or have they even made it that far yet? Thorium is fairly common stuff. Maybe the unbibium is found in certain deposits of thorium for one reason or another? Should be of interest to the geologists as well.

Nothing wrong with being a geek. I like having computers around. :D
 

hermanntrude

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Jun 23, 2006
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one of my links will take you to the paper. I'm not sure how they managed to get it into pdf format and online without it being peer-reviewed yet, and i have heard that they used some fairly unstable compounds for calibrating their instruments so it might not be too valid.

Either way i think it's only a matter of time before someone manages to synthesise some of the elements in the "island of stability".

Not sure why thorium happened to be where they found it, but it's very rare in comparison to thorium (which presumably is why no one found it yet)
 

Walter

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Jan 28, 2007
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The table has grown since I first studied it decades ago. Has anyone predicted how many elements there are that still need to be discovered?
 

hermanntrude

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Jun 23, 2006
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yes. In the OP it states that after 138 elements, electrons would need to move at the speed of light in their orbitals, and so it's thought that element 138 is the highest possible.
 

hermanntrude

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Jun 23, 2006
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the mistake is that in the periodic tabkle above the element 110 is labelled "Unn", which stands for unnilnilium, which means 100, not 110. it should be ununnilium, Uun
 

hermanntrude

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Jun 23, 2006
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I have already thought of new uses for heavier elements, smaller fishing sinkers and paper weights and better armour piercing rounds.

you're probably wrong, darkbeaver. You're thinking of more dense elements. Currently, the most dense element known to man is osmium. density is mass per cubic centimetre. "Heavy" refers to how heavy a single atom is. As it turns out some of the heaviest elements are among the least dense. Element 112 is reported to be a gas, or possibly a liquid, like mercury.
 

Lester

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Sep 28, 2007
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One thing that always bugged me in college- if opposite forces attract and like forces repel why doesn't a atom with two or more protons fly apart?- I've read about gluons(supposedly the force that holds them together)